The atmosphere is roughly 78% nitrogen, 21% oxygen, and 1% other gases including water vapour and CO2.
These proportions stay constant up to about 80 km, but water vapour content varies hugely and is what drives most weather.
ISA gives pilots a fixed baseline to compare real conditions against, so instruments and performance charts mean the same thing everywhere.
Air pressure falls as you climb because there is less air weighing down from above.
Density depends on pressure, temperature and humidity: density increases with higher pressure, and decreases with higher temperature or higher humidity (moist air is less dense than dry air because water vapour molecules are lighter than nitrogen and oxygen molecules).
Clouds form when air is cooled to its dew point (or gains moisture) and condensation nuclei are present. The three main cooling mechanisms are orographic uplift (air forced over high ground), convective heating (surface heating causes air to rise), and frontal lifting (warm air forced up over cooler air at a front). Once air rises past the condensation level it cools at either the Dry Adiabatic Lapse Rate (DALR, 3.0 degrees C per 1000 ft) before saturation, or the Saturated Adiabatic Lapse Rate (SALR, roughly 1.5 degrees C per 1000 ft, varies with temperature) after saturation, because latent heat release slows the cooling.
Compare the Environmental Lapse Rate (ELR, the actual temperature drop with height on the day) to the DALR/SALR of a rising parcel.
The standard ISA average ELR is 1.98 degrees C per 1000 ft (often rounded to 2 degrees C/1000 ft).
Clouds are grouped by height of base: High (CI, CC, CS, bases above 20,000 ft), Medium (AS, AC, bases 6,500-20,000 ft), Low (ST, SC, NS, bases up to 6,500 ft), plus vertical development clouds (CU, CB) which can span all levels. CB (cumulonimbus) is the one to fear - associated with severe turbulence, icing, hail, lightning, microbursts and windshear; a CB needs a towering cumulus stage, a mature stage (precipitation begins, downdraughts) and a dissipating stage.
For precipitation to reach the ground, cloud droplets must grow large enough to overcome updraughts - via the Bergeron-Findeisen process (ice crystals grow at the expense of supercooled water droplets in mixed clouds) or by coalescence (droplets colliding and merging, typical in warm cumuliform cloud). Drizzle falls from stratiform cloud with small water content; showers fall from cumuliform cloud; freezing rain/drizzle occurs when rain falls through a sub-zero layer near the surface and freezes on contact - a serious icing hazard.
An air mass is a large body of air with roughly uniform temperature and humidity, taking on the characteristics of its source region.
A front is the boundary between two air masses of different temperature and density.
Wind gradient (wind shear) is the change of wind speed and/or direction with height, most marked in the lowest few hundred feet above the surface.
Visibility is reported in metres or kilometres and drives whether you can legally fly VFR.
In a METAR, visibility is given as the lowest value observed. Below 5000 m it's reported in metres (steps of 50 m below 800 m, 100 m steps 800-5000 m); at or above 10 km it's reported as 9999.
CAVOK means visibility 10 km or more, no cloud below 5000 ft (or below the highest MSA if higher), and no significant weather.
Fog is cloud (water droplets) sitting at the surface, reducing visibility below 1000 m.
Mist is the same thing but visibility stays 1000 m or more; haze is dry particles, not water droplets.
Radiation fog needs LIGHT wind to form (some turbulence helps deepen it) but STRONG wind destroys it by mixing too much dry air in.
Advection fog is different - it can form and persist in moderate wind because it's driven by the air mass moving over a cold surface, not by radiational cooling.
Airframe icing needs two things together: visible moisture (cloud, rain, drizzle) and a temperature at or below 0°C (icing can occur down to about -40°C).
Carburettor icing can occur even in clear air with no visible moisture, at temperatures up to about +30°C, whenever humidity is high - this is the classic trick question. It's worst at low power settings (closed/partly-closed throttle) because of the extra cooling from fuel vaporisation and pressure drop.
Structural icing is most severe in cumulonimbus and towering cumulus due to large supercooled droplets, and freezing rain/drizzle produces the fastest, most dangerous clear ice buildup, sometimes ahead of a warm front.
A METAR is an actual observed weather report, issued for a specific aerodrome, normally every 30 or 60 minutes. A TAF (Terminal Aerodrome Forecast) is a forecast of expected conditions at an aerodrome, covering a set validity period - usually 9, 24 or 30 hours depending on the airfield.
A METAR gives, in order: station identifier, date/time (as a six-figure group, day then hour and minute UTC, ending in Z), wind direction and speed, visibility, present weather, cloud, temperature and dew point, and QNH. CAVOK replaces visibility, weather and cloud groups when visibility is 10km or more, no cloud below 5000ft (or below the highest minimum sector altitude if higher) and no cumulonimbus or towering cumulus, and no significant weather present.
Wind is given as a three-figure true direction plus a two or three-figure speed in knots, for example 24012KT. Gusts are shown with a G, for example 24012G22KT. Visibility is given in metres up to 9999 (meaning 10km or more) then in whole kilometres. A variable wind direction is shown when the direction varies by 60 degrees or more and speed is above 3kt, coded as VRB.
Cloud is reported in oktas using FEW (1-2 oktas), SCT (3-4), BKN (5-7) and OVC (8), followed by height in hundreds of feet above the aerodrome. NSC means no significant cloud below 5000ft (or MSA) and no CB/TCU. NCD means no cloud detected by an automated station.
TAFs use change groups to show expected variation: BECMG (becoming - a gradual permanent change over a stated period), TEMPO (temporary - fluctuations lasting under an hour at a time, and in total less than half the period), and PROB30 or PROB40 (a probability of 30% or 40% that stated conditions will occur, often combined with TEMPO). FM (from) marks a rapid, significant change and starts a completely new set of conditions from that time.
Don't confuse BECMG (gradual, permanent) with TEMPO (temporary, fluctuating) - BECMG conditions are expected to persist once reached, TEMPO ones come and go. Don't forget CAVOK has strict criteria - all three conditions (visibility, cloud, weather) must be met, not just one. Remember METAR times are actual observation times, TAF times define a validity period, not certainty. Always read wind, visibility and cloud direction of change (e.g. improving vs deteriorating) from the sequence of groups, not just the first one given.
A TAF can be amended (TAF AMD) when actual or expected conditions differ significantly from the original forecast, and a corrected METAR is issued as METAR COR if an error is found in the original.